| STUDIES ON LANGMUIR-BLODGETT FILM OF METAL COMPLEXES(Ⅰ)-PREPARATION AND CHARACTERIZATION OF THE LB FILM OF N-HEXADECYL PYRIDINIUM TETRAKIS(1-PHENYL-3-METHYL-4-BENZOYL-PYRAZOL-5-ONE)EUROPIUM,C_5H_5NC_(16)H_(33)Eu(PMBP)_4 |
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| 作者姓名： | Chun Hui HUANG Xiao Yan ZHU Ke Zhi WANG Guang Xian XU Yu XU Yuan Qi LIU Pei ZHANG Xu Peng WANG |
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| 作者单位： | a Research Center of Rare Earth Chemistry Peking University Beijing 100871;b Institute of Chemistry Academia Sinica Beijing 100082;c Physics Department of Peking University Beijing 100871 |
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| 基金项目： | The Project was Supported by National Natural Science Foundation of China. |
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| 摘 要： | The LB film of the title complex was prepared by dropping a benzene solution of the title complex on the surfaceof water subphase at 25±1℃.The film was deposited in Z type on various hydrophilic pretreated substrates ofquartz,CaF_2 and electronic conductive glass for different purposes.The π-A curve of the film shows that thecross section per molecule is 125 ~2,which indicates that the alkyl chain of the molecule is basically perpendiculalto the surface of the substrate.UV,IR spectra and transmission electronic microscopy of the film were also obtained.
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STUDIES ON LANGMUIR-BLODGETT FILM OF METAL COMPLEXES(Ⅰ)-PREPARATION AND CHARACTERIZATION OF THE LB FILM OF N-HEXADECYL PYRIDINIUM TETRAKIS（1-PHENYL-3-METHYL-4-BENZOYL-PYRAZOL-5-ONE）EUROPIUM,C5H5NC16H33Eu(PMBP)4 |
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| Chun Hui HUANG,Xiao Yan ZHU,Ke Zhi WANG,Guang Xian XU,Yu XU Yuan,Qi LIU,Pei ZHANG,Xu Peng WANG.STUDIES ON LANGMUIR-BLODGETT FILM OF METAL COMPLEXES(Ⅰ)-PREPARATION AND CHARACTERIZATION OF THE LB FILM OF N-HEXADECYL PYRIDINIUM TETRAKIS（1-PHENYL-3-METHYL-4-BENZOYL-PYRAZOL-5-ONE）EUROPIUM,C5H5NC16H33Eu(PMBP)4[J].Chinese Chemical Letters,1991,2(9):741-744. |
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| Authors: | Chun Hui HUANG Xiao Yan ZHU Ke Zhi WANG Guang Xian XU Yu XU Yuan Qi LIU Pei ZHANG Xu Peng WANG |
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| Institution: | a Research Center of Rare Earth Chemistry Peking University Beijing 100871;b Institute of Chemistry Academia Sinica Beijing 100082;c Physics Department of Peking University Beijing 100871 |
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| Abstract: | The LB film of the title complex was prepared by dropping a benzene solution of the title complex on the surface of water subphase at 25±1℃.The film was deposited in Z type on various hydrophilic pretreated substrates of quartz, CaF2 and electronic conductive glass for different purposes.The π-A curve of the film shows that the cross section per molecule is 125 Å2, which indicates that the alkyl chain of the molecule is basically perpendiculal to the surface of the substrate.UV, IR spectra and transmission electronic microscopy of the film were also obtained. |
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