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Mechanism of catalytic hydrogenation of nitrobenzene in an aprotic medium in the presence of quinones
Authors:S. D. Kushch  É. N. Izakovich  M. L. Khidekel'  V. V. Strelets
Affiliation:(1) Branch of Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka
Abstract:Conclusions The hydrogenation of nitrobenzene in an aprotic medium in the presence of quinones is realized by a reduction-protonation mechanism through alternating stages of electron transfer and protonation. The function of proton donor is fulfilled by the corresponding hydroquinones formed from the quinones under the reaction conditions.Translated from IzvÉstiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1500–1505, July, 1981.
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