| 杯芳烃衍生物的合成和性质的研究5 |
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| 引用本文： | 陆国元,李倩,万小宾,胡宏 纹.杯芳烃衍生物的合成和性质的研究5[J].有机化学,2000,20(1):112-115. |
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| 作者姓名： | 陆国元 李倩 万小宾 胡宏 纹 |
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| 作者单位： | 南京大学化学系 |
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| 摘 要： | 通过对特丁基杯(4)芳烃的酚羟基的选择性醚化制备了一系列一烃基，1，3-二烃基和四烃基醚，烃基分别含有缩醛、酰胺、氰基等活泼官能团。醚化反应的区域选择性主要取于使用的碱的种类和反应时间的长短。
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| 关 键 词： | 杯芳烃 选择性 醚化 |
| 修稿时间： | 1998-12-09 |
Studies on synthesis and property of calix [4] arene derivatives 5 |
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| LU Guo-Yuan
,LI Qian
,WAN Xiao- Bin
,HU Hong-Wen.Studies on synthesis and property of calix [4] arene derivatives 5[J].Chinese Journal of Organic Chemistry,2000,20(1):112-115. |
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| Authors: | LU Guo-Yuan LI Qian WAN Xiao- Bin HU Hong-Wen |
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| Institution: | LU Guo-Yuan
,LI Qian
,WAN Xiao- Bin
,HU Hong-Wen
(Department of Chemistry, Nanjing University. 210093 Nanjing) |
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| Abstract: | A series of novel calix4] arenes containing acetal, amid and cyano group respectively have been prepared by the O - alkylation. In reactions of O - alkylation, mono, 1,3 - di and tetra ethers can be obtained respectively as main products by changing reaction conditions. The regio - selectivity depends greatly on the type of bases used and the reaction time. |
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| Keywords: | calixarene derivative synthesis regio- selection etheration |
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