Anomalous structure-luminescence relationship in phosphorescent gold(I) isonitrile neutral complexes |
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| Authors: | Elbjeirami Oussama Omary Mohammad A Stender Matthias Balch Alan L |
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| Institution: | Department of Chemistry, University of North Texas, Denton, TX 76203, USA. |
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| Abstract: | A new compound that exhibits the shortest intermolecular Au...Au distance ever reported for neutral RNCAuX complexes is found to exhibit a counterintuitive higher-energy Au-centered phosphorescence than that in an analogous compound with a much longer Au...Au distance, presumably due to a different extent of excited-state distortion in dimers vs. extended chains. |
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