Synthesis and Structure of Copper(II) Phosphonodithioite Complexes |
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| Authors: | L. I. Kursheva O. N. Kataeva S. V. Perova E. S. Batyeva O. G. Sinyashin R. Freilich |
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| Affiliation: | (1) Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Tatarstan, Russia;(2) Institute of Organic Chemistry, University of Munster, Munster, Germany |
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| Abstract: | A series of new complexes of CuBr with phosphonodithioites were prepared and characterized by NMR and IR spectroscopy. As shown by single crystal X-ray diffraction, diethyl tert-butylphosphonodithioite forms with CuBr a tetrameric cubane-like complex with the monodentate coordination of the organophosphorus ligand via the P atom.__________Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 6, 2005, pp. 903–907.Original Russian Text Copyright © 2005 by Kursheva, Kataeva, Perova, Batyeva, Sinyashin, Freilich. |
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