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Synthetic protocols and building blocks for molecular electronics |
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| Authors: | Nicolai Stuhr-Hansen, Jakob Kryger S rensen, Kasper Moth-Poulsen, J rn Bolstad Christensen, Thomas Bj rnholm,Mogens Br ndsted Nielsen |
| Affiliation: | aDepartment of Chemistry, Nano-Science Center and Molecular Engineering Group, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen, Denmark |
| Abstract: | Simple and readily accessible aryl bromides are useful building blocks for thiol end-capped molecular wires. Thus, 4-bromophenyl tert-butyl sulfide and 1-bromo-4-(methoxymethyl)benzene serve as precursors for a variety of oligo(phenylenevinylene) and oligo(phenyleneethynylene) wires via efficient synthetic transformations as presented in this paper. |
| Keywords: | Molecular electronics Oligo(phenylenevinylene)s Oligo(phenyleneethynylene)s Aryl thiols |
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