A highly efficient catalyst-free protocol for C-H bond activation: sulfamidation of alkyl aromatics and aldehydes |
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Authors: | Borah Arun Jyoti Phukan Prodeep |
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Affiliation: | Department of Chemistry, Gauhati University, Guwahati 781014, Assam, India. |
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Abstract: | A catalyst-free protocol has been developed for amidation of alkyl aromatics and aldehydes using TsNBr(2)via a nitrene transfer process in the presence of a base in excellent yield within a short time. The reaction was found to be selective for secondary and tertiary benzylic C-H bonds and C-H bonds of aldehydic groups. |
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