| 聚-4-氧杂-6,7-双二苯膦基庚基硅氧烷铑配合物的合成及其催化硅氢化性能 |
| |
| 引用本文： | 卢雪然,钟振林,陈远荫.聚-4-氧杂-6,7-双二苯膦基庚基硅氧烷铑配合物的合成及其催化硅氢化性能[J].高等学校化学学报,1990,11(6):561. |
| |
| 作者姓名： | 卢雪然 钟振林 陈远荫 |
| |
| 作者单位： | 武汉大学化学系 |
| |
| 摘 要： | 4-氧杂-6,7-二氯庚基三甲氧基硅烷依次与二苯膦钾、气相法二氧化硅、三氯化铑作用,合成了聚-4-氧杂-6,7-双二苯膦基庚基硅氧烷铑配合物。它对烯烃与取代烯烃的硅氢化反应具有良好的催化活性。
|
| 关 键 词： | 双齿型膦铑配合物 硅氢化 载体催化剂 硅氢加成催化剂 |
| 收稿时间： | 1988-09-26 |
Synthesis of Poly-4-oxa-6,7-bis(diphenylphosphino) heptyl Siloxanc Rhodium Complex and Its Catalytic Hydrosilylation Behavior |
| |
| Lu Xueran,Zhong Zhenlin,Chen Yuanyin.Synthesis of Poly-4-oxa-6,7-bis(diphenylphosphino) heptyl Siloxanc Rhodium Complex and Its Catalytic Hydrosilylation Behavior[J].Chemical Research In Chinese Universities,1990,11(6):561. |
| |
| Authors: | Lu Xueran Zhong Zhenlin Chen Yuanyin |
| |
| Institution: | Department of Chemistry, Wuhan University, Wuhan |
| |
| Abstract: | Poly-4-oxa-6,7-bis(diphenylphosphino)heptyl siloxane rhodium complex was synthesized from 4-oxa-6,7-dichloroheptene-1 via hydrosilylation with trimethoxysilane in the presence of tetrakis (triphenylphosphine)platinum complex as the catalyst, phosphatization with potassium diphenylphos-phide, sequentially, followed by immobilization on fumed silica and then the reaction with rhodium chloride. It exhibited good catalytic activity for the hydrosilylation of olefins, such as decene, do-decene, w-chloroundecene, phenyl allyl ether, allyl benzene, allyl glycidyl ether, styrene, and methyl methacrylate, etc., with triethoxysilane at 90℃. Apossible structure pattern of this silicone-supported bidentate phosphine rhodium complex has been suggested. |
| |
| Keywords: | Bidentate phosphine rhodium complex Hydrosilylation Supported catalyst Hydrosilyla- tion catalyst |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《高等学校化学学报》浏览原始摘要信息 |
| 点击此处可从《高等学校化学学报》下载免费的PDF全文 |
|
