Synthesis and properties of substituted [3-(2-hydroxyphenyl)-1<Emphasis Type="Italic">H</Emphasis>-1,2,4-triazol-1-yl]acetonitriles期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

按检索

Synthesis and properties of substituted [3-(2-hydroxyphenyl)-1<Emphasis Type="Italic">H</Emphasis>-1,2,4-triazol-1-yl]acetonitriles

Authors:	E Yu Shasheva N I Vikrishchuk L D Popov V I Minkin M E Kletskii M Yu Antipin A D Vikrishchuk I E Mikhailov

Institution:	1.Southern Federal University,Rostov-on-Don,Russia;2.Nesmeyanov Institute of Organometallic Compounds,Russian Academy of Sciences,Moscow,Russia;3.Southern Research Center,Russian Academy of Sciences,Rostov-on-Don,Russia

Abstract:	Alkylation of 3-substituted 5-(2-hydroxyphenyl)-1H-1,2,4-triazoles with chloroacetonitrile gave hitherto unknown N-cyanomethyl derivatives whose structure was determined by X-ray analysis and ¹H and ¹³C NMR spectroscopy. Condensation of substituted 3-(2-hydroxyphenyl)-1H-1,2,4-triazol-1-yl]acetonitriles at the activated methylene group with acetone led to the formation of new 3-methyl-2-triazolylbut-2-enenitrile derivatives.

Keywords:
本文献已被 SpringerLink 等数据库收录！