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Volume change during the formation of nanoporous gold by dealloying
Authors:Parida S  Kramer D  Volkert C A  Rösner H  Erlebacher J  Weissmüller J
Affiliation:Forschungszentrum Karlsruhe, Karlsruhe, Germany.
Abstract:We report a macroscopic shrinkage by up to 30 vol % during electrochemical dealloying of Ag-Au. Since the original crystal lattice is maintained during the process, we suggest that the formation of nanoporous gold in our experiments is accompanied by the creation of a large number of lattice defects and by local plastic deformation.
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