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Solvent extraction separation of uranium(VI) with dibenzo-24-crown-8
Authors:B S Mohite  J M Patil  D N Zambare
Institution:(1) Environmental Analytical Chemistry Laboratory, Department of Chemistry, Shivaji University, 416 004 Kolhapur, (India)
Abstract:Uranium(VI) was quantitatively extracted with 0.01M DB-24-crown-8 in nitrobenzene from 6 to 10M hydrochloric acid. From the organic phase uranium was stripped with 2M nitric acid and determined spectrophotometrically with PAR at 530 nm. Uranium(VI) was separated from a large number of elements in binary mixtures as well as from multicomponent mixtures. The method was extended to the analysis of uranium in geological samples and animal bone.
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