| Synthesis and Structural Characterization of One New Polyoxotungstate Connected via Potassium Cations with aThree-dimensional Framework: H_6Na_2K_4(H_2W_(12)O_(42))Cl_2·14H_2O |
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| 引用本文： | 刘颖,窦建民,王大齐,张宪玺,李大成,周雷,徐峰. Synthesis and Structural Characterization of One New Polyoxotungstate Connected via Potassium Cations with aThree-dimensional Framework: H_6Na_2K_4(H_2W_(12)O_(42))Cl_2·14H_2O[J]. 结构化学, 2007, 26(6): 721-726 |
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| 作者姓名： | 刘颖 窦建民 王大齐 张宪玺 李大成 周雷 徐峰 |
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| 作者单位： | College of Chemistry and Chemical Engineering Liaocheng University，College of Chemistry and Chemical Engineering Liaocheng University，College of Chemistry and Chemical Engineering Liaocheng University，College of Chemistry and Chemical Engineering Liaocheng University，College of Chemistry and Chemical Engineering Liaocheng University，College of Chemistry and Chemical Engineering Liaocheng University，College of Chemistry and Chemical Engineering Liaocheng University，Liaocheng 252059 China，Liaocheng 252059 China，Liaocheng 252059 China，Liaocheng 252059 China，Liaocheng 252059 China，Liaocheng 252059 China，Liaocheng 252059 China |
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| 基金项目： | The work was supported by NNSFC (No. 20501011)，Liaocheng University (31801) |
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| 摘 要： | One new polyoxotungstate complex H_6Na_2K_4(H_2W_(12)O_(42))Cl_2·14H_2O 1 has been prepared in the beaker solution and characterized by elemental analysis and IR spectroscopy. Crystal data: H36Cl2K4W12Na2O56, Mr = 3411.77, monoclinic, space group P21/c, a = 11.5734(16), b = 14.3136(19), c = 15.459(2) , β = 105.601(2)°, V = 2466.5(6)3, Z = 2, Dc = 4.594 g/cm3, F(000) = 3008, μ = 28.447 mm-1, R = 0.0574 and wR = 0.1239 (I > 2σ(I)). Single-crystal X-ray diffraction analysis results reveal that a three-dimensional architecture in the title compound is constructed from the H2W12O4210- units linked by potassium.
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Synthesis and Structural Characterization of One New Polyoxotungstate Connected via Potassium Cations with aThree-dimensional Framework: H_6Na_2K_4(H_2W_(12)O_(42))Cl_2·14H_2O |
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| LIU Ying,DOU Jian-Min,WANG Da-Qi,ZHANG Xian-Xi,LI Da-Cheng,ZHOU Lei,XU Feng,. Synthesis and Structural Characterization of One New Polyoxotungstate Connected via Potassium Cations with aThree-dimensional Framework: H_6Na_2K_4(H_2W_(12)O_(42))Cl_2·14H_2O[J]. Chinese Journal of Structural Chemistry, 2007, 26(6): 721-726 |
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| Authors: | LIU Ying DOU Jian-Min WANG Da-Qi ZHANG Xian-Xi LI Da-Cheng ZHOU Lei XU Feng |
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| Abstract: | One new polyoxotungstate complex H_6Na_2K_4(H_2W_(12)O_(42))Cl_2·14H_2O 1 has been prepared in the beaker solution and characterized by elemental analysis and IR spectroscopy. Crystal data: H36Cl2K4W12Na2O56, Mr = 3411.77, monoclinic, space group P21/c, a = 11.5734(16), b = 14.3136(19), c = 15.459(2) , β = 105.601(2)°, V = 2466.5(6)3, Z = 2, Dc = 4.594 g/cm3, F(000) = 3008, μ = 28.447 mm-1, R = 0.0574 and wR = 0.1239 (I > 2σ(I)). Single-crystal X-ray diffraction analysis results reveal that a three-dimensional architecture in the title compound is constructed from the H2W12O4210- units linked by potassium. |
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| Keywords: | polyoxotungstate potassium X-ray analysis three-dimensional architecture |
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