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Magnesium iron aluminum hydroxosalts and oxide catalysts for oxidative dehydrogenation of alkanes and alcohols |
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| Authors: | O N Krasnobaeva I P Belomestnykh G V Isagulyants T A Nosova T A Elizarova D F Kondakov V P Danilov |
| Institution: | (1) Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia;(2) Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, Moscow, 119991, Russia |
| Abstract: | Methods are developed for the synthesis of precursors for oxide catalysts containing iron hydroxocarbonate and magnesium aluminum hydroxocarbonate with hydrotalcite-type layered structure and decavanadate and paramolybdate ions in anionic interlayers. These precursors are used to synthesize oxide catalysts for oxidative dehydrogenation of alcohols and alkanes with high selectivity and good yields of the desired product in conversion of ethane to ethylene and alcohols to carbonyl compounds. |
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