Adsorption and hydrogenation of unsaturated aldehydes over rhodium black |
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| Authors: | A M Pak V F Vozdvizhenskii S M Turganbaeva T D Levintova and S R Konuspaev |
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| Institution: | (1) Institute of Organic Catalysis and Electrochemistry, Alma-Ata, USSR |
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| Abstract: | Hydrogenation selectivity of conjugated ethylenic bonds of unsaturated aldehydes over rhodium black is shown to be determined by intramolecular interactions in surface complexes due to the electronic structure of the initial unsaturated aldehydes.
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