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Electrical and structural properties enhancement in plasticized high Tg polymers using metal salts |
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| Authors: | Amit Sachdeva Rahul Singh Bhaskar Bhattacharya Pramod K. Singh |
| Affiliation: | 1. Department of Nanotechnology, School of Electrical and Electronics Engineering, Lovely Professional University, Phagwara, India;2. Material Research Laboratory, School of Engineering and Technology, Sharda University, Greater Noida, India;3. Department of Physics, Faculty of Science, Centre for Ionics University of Malaya, University of Malaya, Kuala Lumpur, Malaysia;4. Material Research Laboratory, School of Engineering and Technology, Sharda University, Greater Noida, India |
| Abstract: | Plasticized polymer electrolyte composite has been prepared in the form of a film by solution casting method. Poly (ethyl methacrylate) (PEMA) acts as a host polymer and is doped with Sodium Iodide (NaI). Ethylene carbonate (EC) added as a plasticizer and also enhances amorphicity of the polymer electrolyte. The electrical conductivity of the PEMA+NaI was evaluated using complex impedance spectroscopy. Maximum ionic conductivity obtained at room temperature was 8.75 × 10?6 S/cm with the composition of PEMA: NaI (30%) + 60% EC. The conductivity further increased with increase in temperature and moved up to 5.8 × 10?5 S/cm. Scanning electron microscopy was used to study the surface morphology of the composite film. Fourier transform infrared ray and X-ray diffraction data confirmed the complexation of material. |
| Keywords: | Polymer electrolyte composite plasticizer impedance measurement SEM |