A chemoenzymatic total synthesis of the structure assigned to the alkaloid (+)-montabuphine |
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Authors: | Matveenko Maria Banwell Martin G Willis Anthony C |
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Institution: | Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia. |
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Abstract: | An enantioselective synthesis of the structure, 3, assigned to the alkaloid (+)-montabuphine has been achieved using the readily available metabolite 4 as starting material. A comparison of the physical and spectral data recorded on compound 3 with those reported for (+)-montabuphine suggests that they are different compounds. |
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