Extraordinary circularly polarized luminescence activity exhibited by cesium tetrakis(3-heptafluoro-butylryl-(+)-camphorato) Eu(III) complexes in EtOH and CHCl3 solutions |
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| Authors: | Lunkley Jamie L Shirotani Dai Yamanari Kazuaki Kaizaki Sumio Muller Gilles |
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| Institution: | Department of Chemistry, San José State University, San José, California 95192-0101, USA. |
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| Abstract: | The largest CPL activity ever measured was observed for cesium tetrakis(3-heptafluoro-butylryl-(+)-camphorato) Eu(III) complexes in EtOH and CHCl3 solutions substantiating the stereospecific formation of chiral Delta-SAPR-(C4) configuration with the aid of Cs+...FC (fluorocarbon) interactions more clearly than the exciton CD spectra. |
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