Microwave-assisted solvent-free synthesis of 1,1-diacetates catalyzed by SbCl3 from aldehydes and acetic anhydride |
| |
| Authors: | R Xu J Zhang Y Tian J Zhou |
| |
| Institution: | 1. School of Chemical Engineering, Shandong Institute of Light Industry, Jinan, 250353, P. R. China
2. School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, P. R. China
|
| |
| Abstract: | Microwave-assisted synthesis of a variety of 1,1-diacetates catalyzed by SbCl3 from corresponding aldehydes and acetic anhydride was reported. Only 10 mol% of catalyst was sufficient to push the reaction forward and high amounts of the catalyst did not improve the yields to a great extent. The present protocol offered several advantages including low cost of the catalyst, high yields, short reaction time and simple work-up procedure. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
