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Dissolution of rubbery and glassy polymers
Authors:J S Vrentas  C M Vrentas
Abstract:A mathematical model is formulated for solvent dissolution of rubbery and glassy polymers. An exact solution to the problem is derived for the constant diffusivity case, and a weighted residual solution is developed for the case of a concentration-dependent diffusion coefficient. The solution is used to calculate concentration profiles, dissolution curves, dissolution half-times, and pseudointerface positions at various times. © 1998 John Wiley & Sons, Inc. J. Polym. Sci. B Polym. Phys. 36: 2607–2614, 1998
Keywords:polymer dissolution  rubbery polymers  glassy polymers
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