Addition of polyhaloalkanes to 1-vinylsilatrane |
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| Authors: | M. G. Voronkov L. P. Petukhov S. N. Adamovich V. P. Baryshok V. I. Rakhlin B. Z. Shterenberg R. G. Mirskov |
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| Affiliation: | (1) Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR |
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| Abstract: | Conclusions Polyhaloalkanes react readily with 1-vinylsilatrane upon photoinitiation or in the presence of peroxides with almost quantitative formation of the products of the regiospecific addition of the perhaloalkyl radical to the terminal carbon atom of the vinyl group.Deceased.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 204–205, January, 1987. |
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