Characterization of Lignin Compounds at the Molecular Level: Mass Spectrometry Analysis and Raw Data Processing |
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Authors: | Ruochun Zhang Yulin Qi Chao Ma Jinfeng Ge Qiaozhuan Hu Fu-Jun Yue Si-Liang Li Dietrich A. Volmer |
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Affiliation: | 1.Institute of Surface-Earth System Science, School of Earth System Science, Tianjin University, Tianjin 300072, China; (R.Z.); (C.M.); (J.G.); (Q.H.); (F.-J.Y.); (S.-L.L.);2.Tianjin Key Laboratory of Earth Critical Zone Science and Sustainable Development in Bohai Rim, Tianjin University, Tianjin 300072, China;3.Department of Chemistry, Humboldt-Universität zu Berlin, 12489 Berlin, Germany; |
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Abstract: | Lignin is the second most abundant natural biopolymer, which is a potential alternative to conventional fossil fuels. It is also a promising material for the recovery of valuable chemicals such as aromatic compounds as well as an important biomarker for terrestrial organic matter. Lignin is currently produced in large quantities as a by-product of chemical pulping and cellulosic ethanol processes. Consequently, analytical methods are required to assess the content of valuable chemicals contained in these complex lignin wastes. This review is devoted to the application of mass spectrometry, including data analysis strategies, for the elemental and structural elucidation of lignin products. We describe and critically evaluate how these methods have contributed to progress and trends in the utilization of lignin in chemical synthesis, materials, energy, and geochemistry. |
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Keywords: | lignin mass spectrometry ionization data processing structural information |
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