Asymmetric synthesis of highly substituted gamma-amino acids from allyltitanium sulfoximines |
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| Authors: | Köhler Franz Gais Hans-Joachim Raabe Gerhard |
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| Institution: | Institut für Organische Chemie der Rheinisch-Westf?lischen Technischen Hochschule Aachen, Landoltweg 1, D-52056 Aachen, Germany. |
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| Abstract: | structure: see text]. Asymmetric syntheses of the highly substituted protected gamma-amino acids 10a, 10b, 18, and 21 have been developed starting from the allyltitanium sulfoximines V and VI, respectively, and furan-2-carbaldehyde. |
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