Reaction of ferrocene with bromoadamantane |
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Authors: | D N Kravtsov V D Vil'chevskaya P V Petrovskii Yu Yu Gorelikova |
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Institution: | 1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow
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Abstract: | 1. |
Ferrocene reacts with bromoadmantane in the presence of A1Cl3 to give mono- and 1,1-diadamantylferrocene.
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Acylation of adamantylferrocene with raonoethyl o-phthaloyl chloride takes place in the 3-position of the substituted ferrocene ring, and to some extent in the free cyclopentadienyl ring.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1130–1133, May, 1988. |
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Keywords: | |
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