Hydrothermal syntheses and crystal structure of a novel one-dimensional Pb(II) coordination polymer with chenodeoxycholic acid ligand |
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Authors: | Q. Guan S. Liu |
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Affiliation: | 1. Nanjing College of Chemical Technology, No. 625, Geguan Road, Luhe, Nanjing, 210048, P.R. China
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Abstract: | A novel 1D chain-like coordination polymer, {[Pb(CDCA)2(DMF)] · DMF · 2H2O]} n (I) (HCDCA = chenodeoxycholic acid, DMF = dimethyl formamide), has been synthesized by hydrothermal method and characterized by single crystal X-ray diffraction, IR spectroscopy, and elemental analysis (CIF file CCDC no. 996098). X-ray diffraction analyses indicated that I displays distorted octahedral metal centers with secondary building units [Pb(CDCA)2(DMF)] bridged by a pair of μ2-COO?-bridges. In the crystal, interchain O-H?O hydrogen bonds are present and assemble the neighboring 1D chain into a (4,4) sql type three-dimensional (3D) supramolecular topological network. |
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