Facile functionalization of polypeptides by thiol-yne photochemistry for biomimetic materials synthesis |
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| Authors: | Huang Yugang Zeng Yonghong Yang Jianwen Zeng Zhaohua Zhu Fangming Chen Xudong |
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| Affiliation: | Institute of Polymer Science, DSAPM Lab, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, GuangZhou, China. |
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| Abstract: | Rapid and highly efficient side-chain functionalization of polypeptides was achieved via combination of ring-opening polymerization of a new clickable monomer of γ-propargyl-L-glutamate N-carboxyanhydride (PLG-NCA) and thiol-yne photochemistry, which provides a convenient and universal route to prepare diverse polypeptide-based biomimetic hybrid materials. |
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