Fabrication of mesoporous polymer monolith: a template-free approach |
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Authors: | Okada Keisuke Nandi Mahasweta Maruyama Jun Oka Tatsuya Tsujimoto Takashi Kondoh Katsuyoshi Uyama Hiroshi |
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Affiliation: | Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita 565-0871, Japan. |
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Abstract: | Mesoporous polyacrylonitrile (PAN) monolith has been fabricated by a template-free approach using the unique affinity of PAN towards a water/dimethyl sulfoxide (DMSO) mixture. A newly developed Thermally Induced Phase Separation Technique (TIPS) has been used to obtain the polymer monoliths and their microstructures have been controlled by optimizing the concentration and cooling temperature. |
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