Crystal structure of [WI2(CO)3{P(OMe)3}2] |
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| Authors: | Paul K. Baker Michael B. Hursthouse Latifah A. Latif K.M. Abdul Malik |
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| Affiliation: | (1) Department of Chemistry, University of Wales Bangor, Gwynedd, LL57 2UW, UK;(2) Department of Chemistry, University of Wales, Cardiff, PO Box 912, Park Place, Cardiff, CF1 3TB Wales, U.K.;(3) Centre for Foundation Studies in Science, University of Malaya, 50603 Kuala Lumpur, Malaysia |
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| Abstract: | [WI2(CO)3{P(OMe)3}2]crystallizes in the orthorhombic space group Pca21, with a = 26.924(5), b = 10.726(2), c = 14.136(3) Å, and Z = 8. There are two molecules in the asymmetric unit, the metal atoms in each case being seven-coordinate with a capped fac-(CO)3 octahedral geometry. The molecular dimensions in the two molecules are nearly identical. The W–P distance to the capping atom 2.397 Å (average) is significantly shorter than the other W–P distance, 2.525 Å (average). |
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| Keywords: | Tungsten(II) diiodo carbonyl trimethylphosphite crystal structure |
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