首页 | 本学科首页   官方微博 | 高级检索  
     


Crystal structure of [WI2(CO)3{P(OMe)3}2]
Authors:Paul K. Baker  Michael B. Hursthouse  Latifah A. Latif  K.M. Abdul Malik
Affiliation:(1) Department of Chemistry, University of Wales Bangor, Gwynedd, LL57 2UW, UK;(2) Department of Chemistry, University of Wales, Cardiff, PO Box 912, Park Place, Cardiff, CF1 3TB Wales, U.K.;(3) Centre for Foundation Studies in Science, University of Malaya, 50603 Kuala Lumpur, Malaysia
Abstract:[WI2(CO)3{P(OMe)3}2]crystallizes in the orthorhombic space group Pca21, with a = 26.924(5), b = 10.726(2), c = 14.136(3) Å, and Z = 8. There are two molecules in the asymmetric unit, the metal atoms in each case being seven-coordinate with a capped fac-(CO)3 octahedral geometry. The molecular dimensions in the two molecules are nearly identical. The W–P distance to the capping atom 2.397 Å (average) is significantly shorter than the other W–P distance, 2.525 Å (average).
Keywords:Tungsten(II)  diiodo  carbonyl  trimethylphosphite  crystal structure
本文献已被 SpringerLink 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号