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Anthracene derivatives bearing sulfur atoms or selenium atoms as fluorescent chemosensors for Cu and Hg: different selectivity induced from ligand immobilization onto anthracene
Authors:Yoon Ju Lee  Dongwon Seo  Ji Young Kwon  Guiyoup Son  Min Sun Park  Yun-Hee Choi  Jung Hyun Soh  Ha Na Lee  Kap Duk Lee  Juyoung Yoon  
Institution:

aDivision of Nano Science and Department of Chemistry, Ewha Womans University, 11-1 Daehyon-Dong, Sodaemun-Ku, Seoul 120-750, Republic of Korea

bDepartment of Chemistry, Dongguk University, Kyungju, Kyungbuk 780-714, Republic of Korea

Abstract:Two new selenium containing anthracene derivatives and two new sulfur containing anthracene derivatives were synthesized as fluorescent chemosensors for Hg2+ and Cu2+. Compound 1 displayed a highly selective chelation enhanced fluorescence quenching (CHEQ) effect only with Cu2+, on the other hand, compounds 3 and 4 displayed highly selective chelation enhanced fluorescence (CHEF) effects only with Hg2+ among the metal ions examined.
Keywords:
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