Thiazolidine-4-carboxylic acid and 2-aminothiazoleethanoic acid as ligands. The synthesis, magnetic, e.p.r. and spectral properties of copper(II) complexes |
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| Authors: | Krystyna Giełzak-Koćwin Walter Wojciechowski |
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| Affiliation: | (1) Institute of Chemistry, Pedagogical University, PL-42-201 Cz!["eogon"]("/content/p352188g6460m363/xlarge281.gif") stochowa, Poland;(2) Institute of Inorganic Chemistry and Metallurgy of Rare Elements, Technical University, PL-57-670 Wroc!["lstrok"]("/content/p352188g6460m363/xlarge322.gif") aw, Poland |
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| Abstract: | Summary Two complexes formed from CuII acetate and thiazolidine-4-carboxylic acid (4-TCA) and 2-amino-4-thiazoleethanoic acid (ATAA) have been prepared and characterized by magnetic and spectroscopic techniques. The influence of the nature of ligands and solvents upon CuII e.p.r. properties was investigated for these compounds, Spin-Hamiltonian parameters from these data enabled suggestions concerning the structure of these complexes and the binding ability of the ligands. |
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