Abstract: | Bis(Trifluoromethyl)diazomethane undergoes [3+2] cycloaddition with activated alkenes and alkynes regiospecifically to give substituted pyrazolines and pyrazoles.A. N. Nesmeyanov Institute of Organometallic Compounds, Russian Academy of Sciences, 117813 Moscow. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 2, pp. 452–455, February, 1992. |