A self-assembling hexameric spheroid with variable degrees of hydration |
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| Authors: | Jason Ashmore Roger Bishop Donald C Craig Marcia L Scudder |
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| Institution: | 1. School of Chemistry, The University of New South Wales, UNSW Sydney, NSW, 2052, Australia
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| Abstract: | The V-shaped racemic compound 4,12-dinitro-6,7,14,15-tetrahydro-6,14-methanocycloocta1,2-b:5,6-b??]diquinoline 2 crystallises from solvents of differing water content as a centrosymmetric spheroidal hexamer in the form of a series of isostructural clusters (2)6·(water) x X-ray structures of these crystals in space group $ R\bar{3} $ show that they can exhibit an extent of hydration anywhere throughout the composition range x = 0 to 1. |
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