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Reaction of perfluoro-2-methylpent-2-ene with azoles |
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| Authors: | G G Furin A V Rogoza |
| Institution: | (1) Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent’eva, 630090 Novosibirsk, Russian Federation |
| Abstract: | Perfluoro-2-methylpent-2-ene reacts with pyrazole, imidazole, 1,2,4-triazole, and benzotriazole to give products of the replacement of the vinylic fluorine atom. In the case of imidazole, the product of allylic fluorine substitution, 1,3-bisimidazolylperfluoro-2-methylpent-2-ene, is also formed. The structures of the products were confirmed by spectral data. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 835–837, April, 1997. |
| Keywords: | perfluoro-2-methylpent-2-ene NMR spectroscopy nucleophilic substitution 1-(perfluoro-1-ethyl-2-methylprop-1-enyl)imidazole -pyrazole -1 2 4-trizole -benzotriazole |
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