Telluronium salts mediated aziridination of chiral N-tert-butylsulfinylimines: highly stereoselective synthesis of optically active vinylaziridines |
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| Authors: | Zheng Jun-Cheng Liao Wei-Wei Sun Xiao-Xia Sun Xiu-Li Tang Yong Dai Li-Xin Deng Jin-Geng |
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| Affiliation: | State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, PR China. |
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| Abstract: | [reaction: see text] Optically active cis-2-substituted vinylaziridines are synthesized by the reaction of N-tert-butylsulfinylimines with telluronium ylides with excellent diastereoselectivity in good to excellent yields. |
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