|
|||||
|
|
An interpretation of the polarized crystal spectra of Mn(II) and Co(II) in D2h symmetry |
|
| Authors: | Martha J Lindbeck John E Drumheller Kenneth Emerson |
| Institution: | Department of Chemistry, Montana State University, Bozeman, Montana 59717 USA;Department of Physics, Montana State University, Bozeman, Montana 59717 USA;Department of Chemistry, Montana State University, Bozeman, Montana 59717 USA |
| Abstract: | Crystals of TMAMxM′1?xCl3 · 2H2O where TMA = (CH3)3NH+ and M = Mn2+, M′ = Co2+ are strikingly pleochroic. The polarized spectra of these highly colored orthorhombic salts are reported and transition assignments are made based on D2h symmetry. Peaks in the Mn(II) spectra are explained as electric dipole transitions while peaks in the Co(II) spectra are explained as magnetic dipole transitions. |
| Keywords: | To whom correspondence should be addressed |
| 本文献已被 ScienceDirect 等数据库收录！ | |