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| 二(1-正丁基茚基)四羰基二钌的合成与晶体结构 | |
| 引用本文： | 马志宏,李放,刘晓焕,林进. 二(1-正丁基茚基)四羰基二钌的合成与晶体结构[J]. 有机化学, 2009, 29(8): 1294-1297 |
| 作者姓名： | 马志宏 李放 刘晓焕 林进 |
| 作者单位： | 1. 河北师范大学化学与材料科学学院,石家庄,050016;河北医科大学基础医学院,石家庄,050017 2. 河北师范大学化学与材料科学学院,石家庄,050016 |
| 基金项目： | 河北省自然科学基金，河北师范大学博士启动基金 |
| 摘 要： | 由C9H6-n-BuH与Ru3(CO)12在二甲苯中加热回流, 合成了一个新的双核配合物(η5-C9H6-n-Bu)2Ru2(CO)4. 通过元素分析、红外光谱、核磁共振氢谱对其结构进行了表征. 用X射线单晶衍射法测定了(η5-C9H6-n-Bu)2Ru2(CO)4的结构, 结果表明: 晶体属于三斜晶系, Pī空间群, a＝0.8880(5) nm, b＝1.2337(8) nm, c＝1.3235(8) nm, α＝83.054(12)°, β＝76.683(10)°, γ＝77.036(12)°, V＝1.3713(15) nm3, Dc＝1.588 g•cm－3, m＝1.134 mm－1, F(000)＝658, Z＝2, R1＝0.0993, wR2＝0.2459. |
| 关 键 词： | 羰基钌 茚基 二聚物 结构 X射线衍射 |
| 收稿时间： | 2008-11-27 |
| 修稿时间： | 2009-05-13 |
Synthesis and Crystal Structure of Di(1-butylindenyl) Tetracarbonyl Diruthenium |
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| Ma Zhihong,Li Fang,Liu Xiaohuan,Lin Jin. Synthesis and Crystal Structure of Di(1-butylindenyl) Tetracarbonyl Diruthenium[J]. Chinese Journal of Organic Chemistry, 2009, 29(8): 1294-1297 | |
| Authors: | Ma Zhihong Li Fang Liu Xiaohuan Lin Jin |
| Affiliation: | (a College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050016) (b College of Basic Medicine, Hebei Medical University, Shijiazhuang 050017) |
| Abstract: | A new dinuclear complex (η5-C9H6-n-Bu)2Ru2(CO)4 has been synthesized by the reaction of C9H6-n-BuH with Ru3(CO)12 in refluxing xylene, and its molecular structure was characterized by elemental analysis, IR, 1H NMR spectra and X-ray diffraction. Crystal data for this compound: triclinic, space group Pī, a＝0.8880(5) nm, b＝1.2337(8) nm, c＝1.3235(8) nm, α＝83.054(12)°, β＝76.683(10)°, γ＝77.036(12)°, V＝1.3713(15) nm3, Z＝2, Dc＝1.588 g•cm－3, μ＝1.134 mm－1, F(000)＝658, R1＝0.0993, and wR2＝0.2459. |
| Keywords: | ruthenium carbonyl indenyl dimer structure X-ray diffractio |
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