Temperature-programmed desorption of n-propylbenzene from HNaZSM-5 and Na(Li, K, Rb, Cs) ZSM-5 type zeolites |
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Authors: | M. Otremba and W. Zajdel |
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Affiliation: | (1) Department of Chemistry, Silesian Technical University, 44-101 Gliwice, Poland |
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Abstract: | Adsorption of n-propylbenzene on ZSM-5 type zeolites occurs on both Brönsted and Lewis type acid sites. Alkali cations strongly bind hydrocarbons. One particle of hydrocarbon is adsorbed on one Na+ ion. The strength of the bond depends on the cation radius and decreases in the order: Li>Na>K>Rb>Cs. |
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