Photochemical,thermal, and thermocatalytic reactions of diphenyldiazomethane with dimethyl thiophosphite |
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| Authors: | B. A. Arbuzov A. M. Polozov N. A. Polezhaeva A. Kh. Mustafin Ya. A. Levin É. I. Gol'dfarb |
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| Affiliation: | (1) A. M. Butlerov Institute of Chemistry, V. I. Ul'yanov-Lenin Kazan State University, USSR |
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| Abstract: | Conclusions The direct photolysis of diphenyldiazomethane in dimethyl thiophosphite gave the product of P-H insertion. The thermal reaction leads to the N-dimethoxythiophosphorylhydrazone of benzophenone and O,O-dimethyl S-(diphenylmethyl) thiophosphate. Carbenoid P-H insertion occurred in the thermocatalytic decomposition.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 726–727, March, 1989. |
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