| Synthesis,Crystal Structure and Magnetic Property of a Novel Cu(Ⅱ)-Fluconazole-azide Complex |
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| 作者姓名： | GONG Yun QIN Jian-Bo ZHENG Ling-Ling CAO Rong |
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| 作者单位： | GONG Yun(Department of Chemistry, College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China);QIN Jian-Bo,ZHENG Ling-Ling(Department of Chemistry, College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China);CAO Rong(State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China) |
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| 基金项目： | the Chongqing University Postgraduate Science，Innovation Fund and Innovative Talent Training Project of the Third Stage of"211 Project" of Chongqing University，the Natural Science Young Scholars Foundation of Chongqing University |
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| 摘 要： | The title compound formulated as Cu2(C13H11N6OF2)(N3)3CH3OH was synthesized and structurally characterized by elemental analysis,IR and single-crystal X-ray diffraction.In the structure of the complex,the deprotonated fluconazole and azide anion link two copper centers to construct a binuclear SBU and the azide anion exhibits a μ1,1-coordination mode.Each triazole group of fluconazole links two SBUs and the compound exhibits a chain-like architecture with strong antiferromagnetism.
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| 关 键 词： | 晶体结构 氟康唑 磁学性能 合成 铜 元素分析 射线衍射 链接结构 |
Synthesis, Crystal Structure and Magnetic Property of a Novel Cu(Ⅱ)-Fluconazole-azide Complex |
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| GONG Yun,QIN Jian-Bo,ZHENG Ling-Ling,CAO Rong.Synthesis, Crystal Structure and Magnetic Property of a Novel Cu(Ⅱ)-Fluconazole-azide Complex[J].Chinese Journal of Structural Chemistry,2010,29(8):1260-1264. |
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| Authors: | GONG Yun QIN Jian-Bo ZHENG Ling-Ling CAO Rong |
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| Abstract: | The title compound formulated as Cu2(C13H11N6OF2)(N3)3CH3OH was synthesized and structurally characterized by elemental analysis, IR and single-crystal X-ray diffraction. In the structure of the complex, the deprotonated fluconazole and azide anion link two copper centers to construct a binuclear SBU and the azide anion exhibits a μ1,I-coordination mode. Each triazole group of fluconazole links two SBUs and the compound exhibits a chain-like architecture with strong antiferromagnetism. |
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| Keywords: | fluconazole azide crystal structure synthesis antiferromagnetism |
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