Partial oxidation and oxidative condensation of methane with the participation of N2O on a V2O5/SiO2 catalyst |
| |
Authors: | N I Il'chenko A I Bostan L Yu Dolgikh G I Golodets |
| |
Institution: | (1) L. V. Pisarzhevskii Institute of Physical Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev |
| |
Abstract: | The catalytic reaction of CH4, with N2O at 773–823 K on a V2O5/SiO2 catalyst affords products of the partial oxidation (HCHO and CH3OH), exhaustive oxidation (CO), and oxidative condensation (C2H5OH and CH3CHO) of methane. A mechanism is proposed for the complex reaction, including the intermediate compounds V5+O and V4+CH3OH as common intermediates for all the routes.Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 23, No. 5, pp. 641–646, September–October, 1987. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|