Formation of associates of solvated cations in salt solutions in polar dielectric liquids |
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| Authors: | M A Kazaryan I V Shamanin I V Lomov S Yu Dolgopolov A N Lobanov |
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| Institution: | (1) Theoretical Chemistry Division, Institute of General, Inorganic and Theoretical Chemistry, University of Innsbruck, Innrain 52a, A-6020 Innsbruck, Austria; |
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| Abstract: | Experimental results are presented on excitation of oscillations of polarization charges of solvated ions in an aqueous solution
of a mixture of cerium and lead nitrates under an external asymmetric electric field and the directed motion of solvated cerium
and lead cations, caused by this process. The applicability of the approximation of the existence of a self-consistent electric
field in the solution volume to explain the observed frequency ranges of the manifestation of the effect of electroinduced
selective drift of solvated cations is demonstrated. The results of a theoretical analysis of the possibility of forming associates
from solvated ions are presented. |
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