Iridium nitrosyl complexes of 2-aminophenol derivatives |
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Authors: | Mauro Ghedini Giuliano Dolcetti Bruno Giovannitti |
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Affiliation: | (1) Department of Chemistry, Università della Calabria, 87030 Arcavacata (CS), Italy |
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Abstract: | Summary The synthesis and characterisation of products obtained by the interaction between [Ir(NO)(MeCN)2(PPh3)2]2+ and 2-aminophenol derivatives are reported. Tetracoordinate d8complexes of the type Ir(NO)(2-ap)(PPh3) and pentacoordinate d complexes6of the type [Ir(2-ap)(PPh3)3]+ where 2-ap=2-aminophenol, 2-amino-4-nitrophenol, 2-amino-5-methylphenol, 2-3-aminonaphthol and 2-amino-4-methylphenol are obtained. The Ir(NO)(PPh3)3 complex is always present as a byproduct. Physical properties, i.r. spectra and conductivity data of the complexes are tabulated. Reaction schemes for the formation of the three complexes are proposed and discussed. |
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