Enantioselective allyltitanation. Efficient synthesis of the C1-C14 polyol subunit of amphotericin B |
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| Authors: | BouzBouz S Cossy J |
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| Affiliation: | Laboratoire de Chimie Organique associé au CNRS, ESPCI, 10 rue Vauquelin, 75231 Paris Cedex 05, France. |
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| Abstract: | [structure] An efficient synthesis of the C(1)-C(14) fragment of amphotericin B is described. This synthesis is based on the formation of syn-1,3-diols from enantioselective allyltitanation of unprotected beta-hydroxyaldehydes. |
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