Controlled polymerization of methyl methacrylate in the presence of an FeCl3-complexing agent system |
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| Authors: | S A Bulgakova E S Tumakova Yu D Semchikov |
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| Institution: | 1. Research Institute of Chemistry, Nizhni Novgorod State University, pr. Gagarina 23/5, Nizhni Novgorod, 603950, Russia
2. Nizhni Novgorod State University, pr. Gagarina 23, Nizhni Novgorod, 603950, Russia
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| Abstract: | The controlled polymerization of methyl methacrylate in DMF with participation of FeCl3 and ligands (acrylamide, 1,1,1,3,3,3-hexamethyldisilazane, citric acid, and sulfosalicylic acid) has been studied. It has been shown for the first time that DMF ensures the polymerization of methyl methacrylate in the controlled mode without any other complexing agents. As temperature increases, the rate of the process and the polydispersity of PMMA increase. |
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