Transformations of Tetraazametallocomplexes of Gold(III) in the Presence of Oxidants |
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| Authors: | V A Afanas’eva I V Mironov |
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| Institution: | (1) Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia |
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| Abstract: | The treatment of the macrocyclic tetraazametallocomplexes of gold(III), Au(C9H19N4)]2+ and Au(C14H22N4)]+, with hydrochloric solutions of H2O2 or Ce(SO4)2 results in the substitution of the hydrogen atoms for halogen atoms in the β-position of the six-membered diiminate rings of the ligands. |
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