Electron spin relaxation via vibronic level of rhodium(II) hexacyanide complex in KCl crystal |
| |
Authors: | Neto J A Vugman N V |
| |
Affiliation: | Instituto de Física, Universidade Federal do Rio de Janeiro, Rio de Janeiro 21910-240, RJ, Brazil. |
| |
Abstract: | Electron spin-lattice relaxation rates for the low-spin [Rh(CN)(6)](4-) complex in KCl were measured by the inversion recovery and saturation recovery techniques, in the range of 5 to 30 K. Angular variation experiments indicate that electron spin-lattice relaxation times present axial symmetry. The data fit very well to a relaxation process involving localized anharmonic vibration modes, also responsible for the g tensor temperature dependence. |
| |
Keywords: | |
本文献已被 ScienceDirect PubMed 等数据库收录! |
|