Cobalt(III), copper(II), and nickel(II) complexes of 1-thia-4,7-diazacyclononane-S-oxide |
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| Authors: | Matsuo Nonoyama Kiyoko Nonoyama |
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| Affiliation: | (1) Department of Chemistry, Faculty of Science, Nagoya University, Chikusa, 464 Nagoya, Japan;(2) Konan Junior College, Takaya-cho, Konan-shi, 483 Aichi, Japan |
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| Abstract: | Summary The title complexes [ML2]n+=CoIII, CuII, NiII; L=1-thia-4,7-diazacyclononane-S-oxide) have been prepared and characterized spectroscopically. The sulphoxide group is coordinated through the oxygen atom and the complexes have atrans-O,O geometry. The nickel(II) complex of bis(2-amino-ethyl)sulphoxide has also been studied. |
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