Initial stage of physical ageing in network glasses |
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Authors: | R Golovchak A Ingram A Kozdras M Vlcek C Roiland B Bureau |
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Institution: | 1. Lviv Scientific Research Institute of Materials of SRC “Carat”, 202, Stryjska str. , Lviv , UA-79031 , Ukraine roman_ya@yahoo.com;3. Physics Faculty, Opole University of Technology , 75, Ozimska str., Opole , PL-45370 , Poland;4. Department of General and Inorganic Chemistry, Faculty of Chemistry , University of Pardubice , 532 10 Pardubice , Czech Republic;5. Verres et Céramiques, UMR CNRS 6226 Sciences Chimiques de Rennes, University of Rennes , 1, Campus de Beaulieu, Rennes , 35042 , France |
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Abstract: | An atomistic view on Johari–Goldstein secondary β-relaxation processes responsible for structural relaxation far below the glass transition temperature (Tg ) in network glasses is developed for the archetypal chalcogenide glass, As20Se80, using positron annihilation lifetime, differential scanning calorimetry, Raman scattering and nuclear magnetic resonance techniques. Increased density fluctuations are shown to be responsible for the initial stage of physical ageing in these materials at the temperatures below Tg . They are correlated with changes in thermodynamic parameters of structural relaxation through the glass-to-supercooled liquid transition interval. General shrinkage, occurred during the next stage of physical ageing, is shown to be determined by the ability of system to release these redundant open volumes from the glass bulk through the densification process of glass network. |
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Keywords: | chalcogenide glass positron annihilation lifetime DSC NMR Raman scattering ageing |
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