Synthese von 3-(2,4,5-Trihydroxyphenyl)-DL-alanin |
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Authors: | A Langemann M Scheer |
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Abstract: | Condensation of 2.4.5-trimethoxybenzaldehyde with hydantoin followed by catalytic hydrogenation gave 5-(2.4.5-trimethoxybenzyl)-hydantoin, which was converted to 3-amino-3.4-dihydro-6.7-dihydroxycoumarin by treatment with hydrobromic acid. Hydrolysis of the lactone led to 3-(2.4.5-trihydroxyphenyl)-DL -alanine. |
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