| [Co（2,6-pyridinediformates）2（H2O）3]的合成与晶体结构 |
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| 引用本文： | 李家贵,朱万仁,陈渊,刘国聪,朱宇林,黄肇宇,丁树红.[Co（2,6-pyridinediformates）2（H2O）3]的合成与晶体结构[J].玉林师范学院学报,2010,31(5):65-68. |
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| 作者姓名： | 李家贵 朱万仁 陈渊 刘国聪 朱宇林 黄肇宇 丁树红 |
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| 作者单位： | [1]玉林师范学院化学与生物系副教授,广西玉林537000 [2]玉林师范学院化学与生物系教授,广西玉林537000 [3]玉林师范学院化学与生物系高级实验师,广西玉林537000 [4]玉林师范学院化学与生物系教授博士,广西玉林537000 [5]玉林师范学院化学与生物系硕士研究生,广西玉林537000 |
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| 摘 要： | 合成了2,6-吡啶二甲酸合钴的配合物,通过了元素分析、红外光谱对其结构进行了表征.用X-射线单晶衍射测定了该配合物的晶体和分子结构.配合物晶体为单斜晶系,空间群P 21/c,晶胞参数：a=13.8584（11）,b=10.0806（8）,c=13.6858（10）,α=90.00°,β=115.843（5）°,γ=90.00°,Z=4,V=1720.7（2）3,Dc=1.719g/cm3,μ=1.064mm-1,F（000）=908,差值电子密度最高和最低峰为711和-756e.nm-3.
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| 关 键 词： | 配合物 晶体 表征 |
Synthesis and Crystal Structure of [Co(2,6-pyridinediformates)2 (H2O)3] Complex |
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| LI Jia-gui,ZHU Wan-ren,CHEN Yuan,LIU Guo-cong,ZHU Yu-lin,HUANG Zhao-yu,DING Shu-hong.Synthesis and Crystal Structure of [Co(2,6-pyridinediformates)2 (H2O)3] Complex[J].Journal of Yulin Teachers College,2010,31(5):65-68. |
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| Authors: | LI Jia-gui ZHU Wan-ren CHEN Yuan LIU Guo-cong ZHU Yu-lin HUANG Zhao-yu DING Shu-hong |
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| Institution: | 1,5.Associate Professor,Dept. of Chemistry and Biology,Yulin Normal University,Yulin,Guangxi 537000)(2.Professor,Dept. of Chemistry and Biology,Yulin Normal University,Yulin,Guangxi 537000)(3,6.Senior Experimentalist,Dept. of Chemistry and Biology,Yulin Normal University,Yulin,Guangxi 537000)(4.Ph.D.,Professor,Dept. of Chemistry and Biology,Yulin Normal University,Yulin,Guangxi 537000)(7.Postgraduate,Dept.of Chemistry and Biology,Yulin Normal University,Yulin,Guangxi 537000) |
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| Abstract: | Co（II） Complex of 2,6-pyridinediformates was synthesized.Its crystal and molecular structure was determined by X-ray single crystal diffraction method.A crystal of the said compound was monoclinic with a space group P 21/c,a=13.8584（11）,b=10.0806（8）,c=13.6858（10）,α=90.00°,β=115.843（5）°,γ=90.00°,Z=4,V=1720.7（2）3,Dc=1.719g/cm3,μ=1.064mm-1,F（000）=908.The summit value and minimum of difference of electron density were 711 and-756e.nm-3 respectively. |
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| Keywords: | complex crystal characterization |
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